Yes, if different people in your company deal with the service, e.g. your accounts department and your website developer, it makes sense for them to receive emails that relate to their job function. To add contacts, log into your account and click on the Menu. Under Your Account > Your details, select 'Manage contacts' and then click 'Add Contact'.
You can activate one or a mix of the tailored messages below for each contact:
Balance: Receive a notification when your credit is running low.
Security: Receive error and security notifications on your account.
Billing: Receive any finance-related updates such as invoices.